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Bis(1,5-Cyclooctadiene)Nickel(O)

Chemical Name: BIS(1,5-CYCLOOCTADIENE)NICKEL(0)
CAS: 1295-35-8
Molecular Formula: C16H24Ni
Formula Weight: 275.06
Structure:

Bis(1,5-Cyclooctadiene)Nickel(O) structure

Application:

Catalyst for the cycloaddition of 1,3-dienes.
Used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. The reaction with terminal acetylenes proceeds in high yield and high selectivity. A variety of functional groups are tolerated.